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The smaller sized alkali metals tend to polarise the larger anions (the peroxide and superoxide) because of their smaller size. This appeals to the electrons in the greater intricate anions to amongst its constituent oxygen atoms, forming an oxide ion and an oxygen atom. This will cause lithium to kind the oxide completely on reaction with oxygen at room temperature. This outcome gets to be drastically weaker for that larger sodium and potassium, permitting them to sort the considerably less steady peroxides. Rubidium and caesium, at The underside with the group, are so huge that even the the very least steady superoxides can type. As the superoxide releases by far the most Electrical power when formed, the superoxide is preferentially shaped for the greater alkali metals the place the greater advanced anions will not be polarised. The oxides and peroxides for these alkali metals do exist, but usually do not sort upon direct reaction of the metallic with oxygen at typical situations.[84] Also, the small size in the Li+ and O2− ions contributes for their forming a secure ionic lattice structure.
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Alkyl and aryl derivatives of sodium and potassium usually respond with air. They bring about the cleavage of ethers, producing alkoxides. Compared with alkyllithium compounds, alkylsodiums and alkylpotassiums cannot be created by reacting the metals with alkyl halides because Wurtz coupling happens:[122]: 265
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